Arkema: Developing Intrinsically Fire-Retardant Bio-Based Polymers
Arkema: Developing Intrinsically Fire-Retardant Bio-Based Polymers
Within the THERMOFIRE project, Arkema is pursuing a high-risk, low-TRL approach to revolutionize fire-retardant polyamide 11 (PA11). Unlike traditional methods that mix PA11 with flame-retardant additives, Arkema is inventing a new reactive route to synthesize intrinsically fire-retarded PA11 by incorporating phosphorus-based monomers directly into the polymer backbone.
Innovative Approach:
The strategy focuses on developing phosphorus-containing diacid monomers through a two-step chemical reaction. The DOPO molecule (9,10-dihydro-9-oxa-10 phosphaphenanthrene-10-oxide) was selected for its well-documented reactivity, particularly its P-H bond, which reacts efficiently with double bonds through Kabachnik and Pudovik reactions.
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Highlights of Recent Progress:
1. Synthesis of P-Containing Diacids :
- High-yield synthesis (>95%) of phosphorus-containing
monomers was achieved. - Characterization was conducted using NMR, TGA, and
DSC techniques
2. Polymerization Challenges:
- Monomers were polymerized with bio-based aliphatic DA10 and amino undecanoic acid (Amino 11) using
molten-state polycondensation. - However, SEC analysis revealed low molecular weights and high polydispersity, indicating extensive branching and partial solubility.
- These issues stem from unexpected side reactions caused by grafted DOPO moieties, which are currently under investigation using model molecule approaches.
3. Initial Performance Testing:
- The synthesized bio-based PA11, containing 1 wt%
phosphorus, was processed and tested under the UL94
standard, achieving a V2 ranking due to flaming drips.
Next Steps:
To address the challenges observed, Arkema plans to replace DOPO with two alternative phosphorus-containing building blocks that theoretically reduce side reactions. This transition is expected to yield better polymerization control and improved fire-retardant properties. Arkema’s innovative efforts are paving the way for bio-based, intrinsically fire-retardant materials, a critical advancement for the sustainability goals of the THERMOFIRE project.
Publication date: 02/11/2025